新型含C-P键除草抗生素（±）-膦丝菌素的全合成
Total synthesis of (+/-)-phosphonothrixin, a novel herbicidal antibiotic containing C-P bond.
作者信息
Nakamura K, Kimura T, Kanno H, Takahashi E
机构信息
Nishiki Research Laboratories, Kureha Chemical Industry Co., Ltd., Fukushima, Japan.
出版信息
J Antibiot (Tokyo). 1995 Oct;48(10):1134-7. doi: 10.7164/antibiotics.48.1134.
PMID:7490220
Abstract
Phosphonothrixin (1) is a novel herbicidal agent produced by Saccharothrix sp. ST-888, with a unique structure possessing a C-P bond and an isoprene unit. The total synthesis of this antibiotic was accomplished from methyl (bromomethyl)acrylate in six steps.
摘要
膦丝菌素（1）是由糖丝菌属ST - 888菌株产生的一种新型除草剂，具有独特的结构，含有一个碳 - 磷键和一个异戊二烯单元。这种抗生素的全合成是由甲基（溴甲基）丙烯酸酯经六步反应完成的。
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