Maskos K
Acta Biochim Pol. 1978;25(4):303-9.
It was found that in the interaction of xanthosine with copper(II) nitrogen N-7, and not oxygen atoms of carbonyl groups, is involved. In aqueous solution of XMP, copper(II) interacts not only with N-7 and the phosphate group but also with ribose. In a crystalline copper(II)-XMP complex [Cu(C10H11O9N4P).H2O], only the phosphate group and N-7 are involved.
研究发现,在黄苷与铜(II)的相互作用中,参与的是氮原子N-7,而非羰基的氧原子。在XMP的水溶液中,铜(II)不仅与N-7和磷酸基团相互作用,还与核糖相互作用。在晶体铜(II)-XMP配合物[Cu(C10H11O9N4P).H2O]中,仅磷酸基团和N-7参与其中。