Glausch A, Hahn J, Schurig V
Institut für Organische Chemie, Universität Tübingen, Germany.
Chemosphere. 1995 Jun;30(11):2079-85. doi: 10.1016/0045-6535(95)00085-m.
The enantiomeric ratio (ER) of the chiral polychlorinated biphenyl (PCB) 132 (2,2',3,3',4,6'-hexachlorobiphenyl) was determined in human milk samples. The enantiomers were separated by multidimensional gas chromatography (MDGC), using different achiral columns for pre-separation and a Chirasil-Dex column for enantiomer separation, and quantified by electron-capture detection (ECD) and by mass spectrometry (MS/SIM). The determined enantiomeric ratios varied between 0.45-0.85 (enantiomeric excess: 38-8%).
在人乳样本中测定了手性多氯联苯（PCB）132（2,2',3,3',4,6'-六氯联苯）的对映体比例（ER）。对映体通过多维气相色谱法（MDGC）进行分离，使用不同的非手性柱进行预分离，并使用Chirasil-Dex柱进行对映体分离，通过电子捕获检测（ECD）和质谱（MS/SIM）进行定量。所测定的对映体比例在0.45 - 0.85之间（对映体过量：38 - 8%）。
