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[通过气相色谱/质谱分析法测定人尿液中的群勃龙及其代谢物]

[Trenbolone and its metabolites in human urine by GC/MS analysis].

作者信息

Ye L, Zhang C J, Zhang Y Z, Liu X

机构信息

National Research Institute of Sports Medicine, Beijing.

出版信息

Yao Xue Xue Bao. 1994;29(1):61-7.

PMID:8036900
Abstract

The gas chromatography/mass spectrometric properties of trimethylsilyl ether and trifluoroacetyl ester derivatives of trenbolone, combined with a methoxine group, are presented. The cleavage mechanism and some derivatization problems were observed and discussed. The positive urine of trenbolone acetate was checked with the results of epitrenbolone and possible hydroxy-trenbolone as main metabolites. Also a little trenbolone and possible estra-4,9,11-trien-3,17-dione were found.

摘要

本文介绍了群勃龙的三甲基硅醚和三氟乙酰酯衍生物与甲氧基结合后的气相色谱/质谱特性。观察并讨论了裂解机理和一些衍生化问题。用醋酸群勃龙阳性尿液检测了主要代谢产物表群勃龙和可能的羟基群勃龙的结果。还发现了少量群勃龙和可能的estra-4,9,11-三烯-3,17-二酮。

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