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1H- and 13C-nmr assignments and structural determination of a novel glycoalkaloid from Solanum platanifolium.

作者信息

Puri R, Wong T C, Puri R K

机构信息

Department of Chemistry, University of Missouri, Columbia 65211.

出版信息

J Nat Prod. 1994 May;57(5):587-96. doi: 10.1021/np50107a004.

DOI:10.1021/np50107a004
PMID:8064291
Abstract

Four steroidal glycoalkaloids, solasonine [2], solamargine [3], khasianine [4], and ravifoline [5], with solasodine [1] as the aglycone moiety, have been isolated from Solanum platanifolium. The present study involved the characterization of the novel compound 5 by one- and two-dimensional nmr techniques and has also led to the unambiguous and total 13C- and 1H-nmr assignments of all of these steroidal glycoalkaloids and the direct elucidation of their glycosidic linkages.

摘要

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