Claeys R R, Caldwell R S, Cutshall N H, Holton R
Pestic Monit J. 1975 Jun;9(1):2-10.
Concentrations of chlorinated pesticides and polychlorinated biphenyls (PCB's) were determined in three offshore marine species from the Oregon/Washington coast: pink shrimp, euphausiids, and flatfish; five species of bivalve mollusks from five estuaries along the Oregon coast; several fish species from the Coos Bay and Columbia River estuaries; and a summer run of steelhead from the Rogue River. The compounds p,p'-DDE and PCB's were detected most frequently. Euphausiids and pink shrimp contained approximately 2 ppb (mug/kg) wet-weight DDE and 8 and 25 ppb PCB's, respectively. Offshore flatfish contained an average of 9 ppb DDE and 29 ppb PCB's. DDE residues in estuarine mollusks approximated 0.5 ppb. PCB levels were not detectable (greater than 3 ppb) except in collections from the mouth of the Columbia River where the levels averaged 400 ppb PCB's and 17 ppb DDT. Selected Columbia River where levels averaged 400 ppb PCB's and 17 ppb DDT. Selected Columbia River fish species contained 38 ppb DDE and 480 ppb PCB's; summer-run steel-head in the Rogue River contained 97 ppb DDE and 125 ppb PCB's. PCB chromatograms of most euphausiids closely resembled those of Aroclor 1254. Chromatograms of shrimp and flatfish indicated selective metabolism of two compounds in the Aroclor 1254 formulation. Biphenyls of higher chlorine content were also detected in the shrimp and flatfish.
测定了来自俄勒冈州/华盛顿州海岸的三种近海海洋物种(粉虾、磷虾和比目鱼)、俄勒冈州海岸五个河口的五种双壳贝类软体动物、库斯湾和哥伦比亚河河口的几种鱼类以及罗格河夏季洄游的虹鳟鱼体内的氯化农药和多氯联苯(PCBs)浓度。p,p'-滴滴涕和多氯联苯这两种化合物被检测到的频率最高。磷虾和粉虾体内湿重的滴滴涕含量分别约为2 ppb(微克/千克),多氯联苯含量分别为8 ppb和25 ppb。近海比目鱼体内平均含有9 ppb滴滴涕和29 ppb多氯联苯。河口软体动物体内的滴滴涕残留量约为0.5 ppb。除了从哥伦比亚河河口采集的样本中多氯联苯含量平均为400 ppb、滴滴涕含量为17 ppb外,其他样本中的多氯联苯含量均未检测到(大于3 ppb)。选定的哥伦比亚河鱼类体内含有38 ppb滴滴涕和480 ppb多氯联苯;罗格河夏季洄游的虹鳟鱼体内含有97 ppb滴滴涕和125 ppb多氯联苯。大多数磷虾的多氯联苯色谱图与Aroclor 1254的色谱图非常相似。虾和比目鱼的色谱图表明,Aroclor 1254配方中的两种化合物发生了选择性代谢。在虾和比目鱼中还检测到了氯含量更高的联苯。