Synthesis of methionine carrying a chiral methyl group and its use in determining the steric course of the enzymatic C-methylation of indolepyruvate during indolmycin biosynthesis. - Suppr | 超能文献

Synthesis of methionine carrying a chiral methyl group and its use in determining the steric course of the enzymatic C-methylation of indolepyruvate during indolmycin biosynthesis.

作者信息

Mascaro L, Horhammer R, Eisenstein S, Seller L K, Mascaro K, Floss H G

出版信息

J Am Chem Soc. 1977 Jan 5;99(1):273-4. doi: 10.1021/ja00443a062.

DOI:10.1021/ja00443a062

Abstract

摘要

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Synthesis of methionine carrying a chiral methyl group and its use in determining the steric course of the enzymatic C-methylation of indolepyruvate during indolmycin biosynthesis.

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Isolation and characterization of tryptophan transaminase and indolepyruvate C-methyltransferase. Enzymes involved in indolmycin biosynthesis in Streptomyces griseus.色氨酸转氨酶和吲哚丙酮酸C-甲基转移酶的分离与鉴定。参与灰色链霉菌中吲哚霉素生物合成的酶。

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Demonstration of a C-methylating enzyme in cell free extracts of indolmycin-producing Streptomyces griseus.

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The biosynthesis of indolmycin.

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Directed biosynthesis of new indolmycins.新型吲哚霉素的定向生物合成

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C-Methylation Catalyzed by Fom3, a Cobalamin-Dependent Radical S-adenosyl-l-methionine Enzyme in Fosfomycin Biosynthesis, Proceeds with Inversion of Configuration.由Fom3催化的C-甲基化反应发生了构型翻转，Fom3是磷霉素生物合成中一种依赖钴胺素的自由基S-腺苷-L-甲硫氨酸酶。

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Emerging Diversity of the Cobalamin-Dependent Methyltransferases Involving Radical-Based Mechanisms.钴胺素依赖性甲基转移酶基于自由基机制的新出现的多样性

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Isolation and absolute configuration of indolmycenic acid, an intermediate in the biosynthesis of indolmycin by Streptomyces griseus.吲哚霉素酸的分离及绝对构型，链霉菌属灰色链霉菌合成吲哚霉素生物合成中的一种中间体。

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