一氧化氮水溶液的自氧化动力学
Autoxidation kinetics of aqueous nitric oxide.
作者信息
Ford P C, Wink D A, Stanbury D M
机构信息
Department of Chemistry, University of California, Santa Barbara 97106.
出版信息
FEBS Lett. 1993 Jul 12;326(1-3):1-3. doi: 10.1016/0014-5793(93)81748-o.
PMID:8325356
Abstract
Reports on the kinetics of the autoxidation of aqueous nitric oxide are discussed. It is concluded that the correct rate law is -d[NO]/dt = 4kaq[NO]2[O2] with kaq = 2 x 10(6) M-2.s-1 at 25 degrees c and that a recent report of a rate law zero order in NO is incorrect.
摘要
讨论了关于一氧化氮水溶液自氧化动力学的报告。得出的结论是，正确的速率定律为-d[NO]/dt = 4kaq[NO]2[O2]，其中在25摄氏度时kaq = 2×10(6) M-2·s-1，并且最近一份关于一氧化氮零级速率定律的报告是不正确的。
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