Arroyo C M, Feliciano F, Kolb D L, Keeler J R, Millette S R, Stotts R R
U.S. Army Medical Research Institute of Chemical Defense, Aberdeen Proving Ground, MD 21010-5425.
J Biochem Toxicol. 1993 Jun;8(2):107-10. doi: 10.1002/jbt.2570080208.
The reaction of phosgene with nitrone spin traps was investigated using electron paramagnetic resonance (EPR)/spin trapping techniques. Evidence for the intermediacy of a carbamoyl monochloride intermediate was obtained. Isotopic substitution of 13C-phosgene was employed to verify the hyperfine coupling constant assignments. The implications of these observations on pulmonary damage caused by inhalation of phosgene are mentioned.
利用电子顺磁共振（EPR）/自旋捕获技术研究了光气与硝酮自旋捕获剂的反应。获得了碳酰氯单氯中间体存在的证据。采用13C-光气的同位素取代来验证超精细耦合常数的归属。文中提到了这些观察结果对吸入光气所致肺损伤的影响。
