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Chemically bonded stationary phases that use synthetic hosts containing aromatic binding clefts: HPLC analysis of nitro-substituted polycyclic aromatic hydrocarbons.使用含有芳香族结合裂缝的合成主体的化学键合固定相：硝基取代多环芳烃的高效液相色谱分析。
Proc Natl Acad Sci U S A. 1993 Feb 15;90(4):1190-3. doi: 10.1073/pnas.90.4.1190.
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Spectroscopic properties of some derivatives of polycyclic aromatic hydrocarbons.多环芳烃某些衍生物的光谱性质。
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Detection of nitro-polycyclic aromatic hydrocarbons in liquid chromatography by zinc reduction and peroxyoxalate chemiluminescence.通过锌还原和过氧草酸酯化学发光法在液相色谱中检测硝基多环芳烃。
J Chromatogr. 1984 Dec 21;316:507-18. doi: 10.1016/s0021-9673(00)96179-x.
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Beilstein J Org Chem. 2016 Jan 25;12:125-38. doi: 10.3762/bjoc.12.14. eCollection 2016.

本文引用的文献

1
The extraordinary mutagenicity of nitropyrenes in bacteria.硝化芘在细菌中的超强致突变性。
Mutat Res. 1981 Jul;89(3):187-96. doi: 10.1016/0165-1218(81)90236-6.
2
Molecular structures of porphyrin complexes in solution. An 1H nuclear magnetic resonance spectroscopic investigation of the interaction between 2,4,7-trinitrofluorenone and nickel(II) and cobalt(II) mesoporphyrin IX dimethyl esters.溶液中卟啉配合物的分子结构。2,4,7-三硝基芴酮与镍（II）和钴（II）中卟啉IX二甲酯相互作用的1H核磁共振光谱研究。
J Am Chem Soc. 1973 Jul 11;95(14):4545-51. doi: 10.1021/ja00795a014.
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High-performance liquid chromatographic separation of ring-oxidized metabolites of nitro-polycyclic aromatic hydrocarbons.硝基多环芳烃环氧化代谢物的高效液相色谱分离
J Chromatogr. 1989 Jan 6;461:315-26. doi: 10.1016/s0021-9673(00)94298-5.
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Determination of nitro polynuclear aromatic hydrocarbons in air and diesel particulate matter using liquid chromatography with electrochemical and fluorescence detection.
Anal Chem. 1988 Feb 1;60(3):194-9. doi: 10.1021/ac00154a001.
5
Mutagenicity and carcinogenicity of nitroarenes and their sources in the environment.硝基芳烃的致突变性和致癌性及其在环境中的来源。
Crit Rev Toxicol. 1986;17(1):23-60. doi: 10.3109/10408448609037070.
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Metabolism of nitro-polycyclic aromatic hydrocarbons.
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使用含有芳香族结合裂缝的合成主体的化学键合固定相：硝基取代多环芳烃的高效液相色谱分析。

Chemically bonded stationary phases that use synthetic hosts containing aromatic binding clefts: HPLC analysis of nitro-substituted polycyclic aromatic hydrocarbons.

作者信息

Zimmerman S C, Saionz K W, Zeng Z

机构信息

Department of Chemistry, University of Illinois, Urbana 61801.

出版信息

Proc Natl Acad Sci U S A. 1993 Feb 15;90(4):1190-3. doi: 10.1073/pnas.90.4.1190.

DOI:10.1073/pnas.90.4.1190
PMID:8433981
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC45838/
Abstract

The synthesis of hosts with improved binding affinities for nitroaromatic guests is described. Association constants for several host-guest complexes were measured in chloroform solution and ranged over three orders of magnitude. Two hosts were covalently linked to silica gel to produce chemically bonded stationary phases for HPLC. The use of these phases for HPLC analysis of nitro-substituted polycyclic aromatic hydrocarbons is discussed.

摘要

本文描述了对硝基芳烃客体具有更高结合亲和力的主体的合成。在氯仿溶液中测量了几种主体 - 客体配合物的缔合常数，其范围跨越三个数量级。将两种主体共价连接到硅胶上，以制备用于高效液相色谱（HPLC）的化学键合固定相。讨论了这些固定相在硝基取代的多环芳烃HPLC分析中的应用。