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平面和非平面多环芳烃在液相色谱中各种化学键合固定相上的洗脱行为。

Elution behaviour of planar and non-planar polycyclic aromatic hydrocarbons on various chemically bonded stationary phases in liquid chromatography.

作者信息

Jinno K, Nagoshi T, Tanaka N, Okamoto M, Fetzer J C, Biggs W R

出版信息

J Chromatogr. 1987 Apr 17;392:75-82. doi: 10.1016/s0021-9673(01)94255-4.

DOI:10.1016/s0021-9673(01)94255-4
PMID:3597594
Abstract

The elution behaviour of planar and non-planar polycyclic aromatic hydrocarbons has been studied on various stationary phases in reversed-phase and normal-phase liquid chromatography. The results show that the elution behaviours of the isomer sets which have distinctly different planarities such as triphenylene, triphenylmethane or o-terphenyl reflect the characteristics of the chemically bonded stationary phases. The phases studied included polymeric C18, monomeric C18 (with end capping), monomeric C18 (without end capping), triphenyl, naphthylethyl and pyrenylethyl phases.

摘要

在反相和正相液相色谱中,研究了平面和非平面多环芳烃在各种固定相上的洗脱行为。结果表明,具有明显不同平面度的异构体组(如三亚苯、三苯甲烷或邻三联苯)的洗脱行为反映了化学键合固定相的特性。所研究的固定相包括聚合物C18、单体C18(封端)、单体C18(未封端)、三苯基、萘基乙基和芘基乙基固定相。

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