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过氧化氢漂白剂在各种化学和物理条件下的分解速率。

Decomposition rate of hydrogen peroxide bleaching agents under various chemical and physical conditions.

作者信息

Chen J H, Xu J W, Shing C X

机构信息

Prosthetics Department, Stomatological Hospital, Fourth Military Medical University, Xian, People's Republic of China.

出版信息

J Prosthet Dent. 1993 Jan;69(1):46-8. doi: 10.1016/0022-3913(93)90239-k.

Abstract

The decomposition rate of 30% hydrogen peroxide was measured when hydrogen peroxide was mixed with 36% hydrochloric acid and anaesthesia either in 5:5:1 solution and in a solution of 20% sodium hydroxide at temperatures of 16 degrees to 20 degrees C and at 45 degrees C, respectively. The effect of ferris chloride on the decomposition of hydrogen peroxide was also observed. The decomposition of 30% hydrogen peroxide in sodium hydroxide solution was faster than that in the mixture of hydrochloric acid and ether at low temperature (16 degrees to 20 degrees C). The decomposition of hydrogen peroxide was accelerated by heat. The experiment implies that the bleaching effect of hydrogen peroxide can be achieved without heat by use of a sodium hydroxide solution. Further study on the rationale of the compound of the McInnes solution (hydrogen peroxide, hydrochloric acid, and anaesthesia ether mixed at a ratio of 5:5:1) is needed.

摘要

分别在16摄氏度至20摄氏度以及45摄氏度的温度下,测定了30%过氧化氢与36%盐酸和麻醉剂按5:5:1比例混合的溶液以及在20%氢氧化钠溶液中的分解速率。还观察了氯化铁对过氧化氢分解的影响。在低温(16摄氏度至20摄氏度)下,30%过氧化氢在氢氧化钠溶液中的分解比在盐酸和乙醚混合物中的分解更快。加热会加速过氧化氢的分解。该实验表明,使用氢氧化钠溶液无需加热即可实现过氧化氢的漂白效果。需要进一步研究麦金尼斯溶液(过氧化氢、盐酸和麻醉乙醚按5:5:1比例混合)的化合物原理。

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