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来自犀牛突变小鼠皮肤的新型三酯的组成

Composition of novel triesters from the skin of the rhino mutant mouse.

作者信息

Logani M K, Nhari D B, Davies R E

出版信息

Lipids. 1977 Mar;12(3):283-7. doi: 10.1007/BF02533348.

Abstract

Composition of two novel triesters, derived from the skin of the rhino mutant mouse, is described. Chemical and spectroscopic analysis of the products of pancreatic hydrolysis of the triesters showed that these are comprised predominantly of isomer I (92.7 mole %). The syntheses of two reference compounds, I-O-hexadecanoyl-2-[(14-hexadecanoyloxy)O-tetradecanoyl] 1,2-hexadecanediol (Ia) and 2-O-hexadecanoyl-1-[(14-hexadecanoyloxy)-O-tetradecanoyl]-1,2-hexadecanediol (IIa), corresponding in their structures to isomers I and II of the triester, wax have also been described.

摘要

描述了从犀牛突变小鼠皮肤中提取的两种新型三酯的组成。对这些三酯进行胰腺水解产物的化学和光谱分析表明,它们主要由异构体I(92.7摩尔%)组成。还描述了两种参考化合物的合成,即I-O-十六烷酰基-2-[(14-十六烷酰氧基)O-十四烷酰基]1,2-十六烷二醇(Ia)和2-O-十六烷酰基-1-[(14-十六烷酰氧基)-O-十四烷酰基]-1,2-十六烷二醇(IIa),它们的结构分别与三酯蜡的异构体I和II相对应。

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