Mrevlishvili G M, Kakabadze G R
Biofizika. 1993 Mar-Apr;38(2):253-6.
On the basis of experimental data of DNA heat capacity in a wide range of temperatures the fundamental characteristics of DNA-H(0)0-the enthalpy of helix coil transition at 0(0)K were estimated. H(0)0 = 8.41 +/- 1.6 kJ/MBP. It was shown that a deviation from Nernst theorem (resulting from metastability of the system) was not obtained within the range of experimental error.
基于在很宽温度范围内DNA热容量的实验数据,估算了DNA-H₂O体系的基本特征——0K时螺旋-线团转变的焓。H₀₀ = 8.41±1.6 kJ/MBP。结果表明,在实验误差范围内未观察到与能斯特定理的偏差(由体系的亚稳性导致)。