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来自南瓜瓢虫(Epilachna borealis,瓢虫科)蛹外分泌液中的生育酚乙酸酯。

Tocopheryl acetates from the pupal exocrine secretion of the squash beetle, Epilachna borealis (Coccinellidae).

作者信息

Attygalle A B, Smedley S R, Eisner T, Meinwald J

机构信息

Department of Chemistry, Cornell University, Ithaca, New York 14853-1301, USA.

出版信息

Experientia. 1996 Jun 15;52(6):616-20. doi: 10.1007/BF01969741.

DOI:10.1007/BF01969741
PMID:8698100
Abstract

The oily droplets on the pupal integumental hairs of the squash beetle Epilachna borealis contain a mixture of alpha-, beta-, gamma-, and delta-tocopheryl acetates as major constituents. In addition, the secretion contains a number of minor components that appear to be dehydrocongeners of the major components. This is the first report of the occurrence of acetate esters of any tocopherol in nature.

摘要

北美的南瓜瓢虫(Epilachna borealis)蛹体体表毛发上的油滴含有α-、β-、γ-和δ-生育酚乙酸酯的混合物作为主要成分。此外,该分泌物还含有一些次要成分,这些成分似乎是主要成分的脱氢类似物。这是自然界中首次出现任何生育酚乙酸酯的报道。

相似文献

1
Tocopheryl acetates from the pupal exocrine secretion of the squash beetle, Epilachna borealis (Coccinellidae).来自南瓜瓢虫(Epilachna borealis,瓢虫科)蛹外分泌液中的生育酚乙酸酯。
Experientia. 1996 Jun 15;52(6):616-20. doi: 10.1007/BF01969741.
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本文引用的文献

1
Lipid components in anal scent sacs of three mongoose species (Helogale parvula, Crossarchus obscurus, Suricata suricatta).三种獴科动物(小灵猫、缟灵猫、猫鼬)肛门腺的脂质成分。
J Chem Ecol. 1992 Sep;18(9):1511-24. doi: 10.1007/BF00993225.
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.alpha.-Tocopheryl acetate as an indicator of municipal waste contamination in the environment.
Environ Sci Technol. 1985 Mar 1;19(3):282-5. doi: 10.1021/es00133a014.
3
Azamacrolides: a family of alkaloids from the pupal defensive secretion of a ladybird beetle (Epilachna varivestis).氮杂大环内酯类化合物:源自一种瓢虫(茄二十八星瓢虫)蛹期防御分泌物的生物碱家族。
Proc Natl Acad Sci U S A. 1993 Jun 1;90(11):5204-8. doi: 10.1073/pnas.90.11.5204.
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Gas-phase infrared spectroscopy for determination of double bond configuration of monounsaturated compounds.用于测定单不饱和化合物双键构型的气相红外光谱法。
Anal Chem. 1994 May 15;66(10):1696-703. doi: 10.1021/ac00082a016.
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Helv Chim Acta. 1967 Jul 10;50(5):1376-93. doi: 10.1002/hlca.19670500519.
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[Concerning the chemistry of vitamin E. 7. The stereospecific cyclization of (3'R, 7'R, 11'R)-alpha-tocopherolquinone].
Helv Chim Acta. 1967 May 31;50(4):1168-78. doi: 10.1002/hlca.19670500424.
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[Acylation with bis(acylamides). N-methyl-bis(trifluoroacetamide) and bis(trifluoroacetamide), two new reagents for trifluoroacetylation].[用双(酰酰胺)进行酰化反应。N-甲基双(三氟乙酰胺)和双(三氟乙酰胺),两种新型三氟乙酰化试剂]
J Chromatogr. 1973 Apr 25;78(2):273-9.