Kirkpatrick R J, Brow R K
Department of Geology, University of Illinois, Urbana 61801, USA.
Solid State Nucl Magn Reson. 1995 Oct;5(1):9-21. doi: 10.1016/0926-2040(95)00042-o.
This paper presents a review of the nuclear magnetic resonance (NMR) data for phosphate and phosphate-containing glasses obtained primarily within the past 10 years and of the structural interpretations based on those data. Compositions discussed include P2O5, alkali and alkaline earth phosphates, aluminophosphates, borophosphates, fluorophosphates, and phosphate-containing silicate and aluminosilicate glasses. 31P NMR data, in conjunction with 27Al, 29Si, 11B, 7Li, and 23Na data if appropriate, have proven very powerful in providing direct evidence about the local structural environments present in the these materials and in many cases have allowed interpretation of the physical and chemical behavior of these glasses in terms of polyhedral structures.
本文综述了主要在过去10年内获得的磷酸盐及含磷酸盐玻璃的核磁共振（NMR）数据，以及基于这些数据的结构解释。所讨论的成分包括五氧化二磷、碱金属和碱土金属磷酸盐、铝磷酸盐、硼磷酸盐、氟磷酸盐以及含磷酸盐的硅酸盐和铝硅酸盐玻璃。事实证明，31P NMR数据，若适当地结合27Al、29Si、11B、7Li和23Na数据，在提供有关这些材料中存在的局部结构环境的直接证据方面非常有效，并且在许多情况下能够根据多面体结构解释这些玻璃的物理和化学行为。
