硝酸氯（乙二胺）（6-苯基咪唑并-[2,1-b]噻唑-N7）铂（II）
Chloro(ethylenediamine)(6-phenylimidazo-[2,1-b]thiazole-N7)platinum(II) nitrate.
作者信息
Arvanitis G M, Griffitts A E, Baffic S P, Ho D M
机构信息
Department of Chemistry, Trenton State College, Hillwood Lakes, New Jersey 08650, USA.
出版信息
Acta Crystallogr C. 1996 Feb 15;52 ( Pt 2):319-21. doi: 10.1107/s0108270195010067.
PMID:8829358
Abstract
Platination of 6-phenylimidazo[2,1-b]thiazole at the imidazole N atom to give chloro(ethylenediamine)(6-phenylimidazo[2,1-b] thiazole)platinum(II) nitrate, [PtCl-(C2H8N2)(C11H8N2S)]NO3, is accompanied by a rotation of 49.3 (8) degrees of the phenyl ring and a loss of extended conjugation in the normally planar 6-phenylimidazo[2,1-b]thiazole molecule.
摘要
6-苯基咪唑并[2,1-b]噻唑在咪唑氮原子处发生铂化反应，生成硝酸氯（乙二胺）（6-苯基咪唑并[2,1-b]噻唑）铂（II），即[PtCl-(C₂H₈N₂)(C₁₁H₈N₂S)]NO₃，同时苯环旋转49.3（8）度，且在通常呈平面状的6-苯基咪唑并[2,1-b]噻唑分子中扩展共轭消失。
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