Arvanitis G M, Berardini M E, Parkinson G N, Schneider B S
Department of Chemistry, Trenton State College, Hillwood Lakes, NJ 08650.
Acta Crystallogr C. 1993 Jul 15;49 ( Pt 7):1246-8. doi: 10.1107/s0108270193002471.
Chloro(ethylenediamine)[(-)-2,3,5,6-tetrahydro-6-phenylimidazo[2, 1-b]thiazole]platinum(II) chloride, [PtCl(C2H8N2)(C11H12N2S)]Cl, M(r) = 530.39, orthorhombic, P2(1)2(1)2(1), a = 31.676 (11), b = 8.190 (2), c = 6.6242 (6) A, V = 1718.5 (7) A3, Z = 4, Dx = 2.050 g cm-3, lambda (Mo K alpha) = 0.71069 A, mu = 86.8 cm-1, F(000) = 1016, T = 296 K, final R = 0.030 for 1646 unique observed reflections [F > 4 sigma (F)]. The Pt coordination is square planar, bonded to three N atoms (one from the levamisole and two from the ethylenediamine moiety) and to one Cl atom.
氯(乙二胺)[( - )-2,3,5,6 - 四氢 - 6 - 苯基咪唑并[2,1 - b]噻唑]铂(II)氯化物,[PtCl(C₂H₈N₂)(C₁₁H₁₂N₂S)]Cl,M(r) = 530.39,正交晶系,P2(1)2(1)2(1),a = 31.676 (11),b = 8.190 (2),c = 6.6242 (6) Å,V = 1718.5 (7) ų,Z = 4,Dx = 2.050 g cm⁻³,λ(Mo Kα) = 0.71069 Å,μ = 86.8 cm⁻¹,F(000) = 1016,T = 296 K,对于1646个独特的观测反射[F > 4σ(F)],最终R = 0.030。铂的配位为平面正方形,与三个N原子(一个来自左旋咪唑,两个来自乙二胺部分)和一个Cl原子键合。