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X-ray structure of a compound of cobalt with uridine 5'-monophosphate. Evidence for metal-phosphate bonding only.

作者信息

Cartwright B A, Goodgame D M, Jeeves I, Skapski A C

出版信息

Biochim Biophys Acta. 1977 Jul 15;477(2):195-8. doi: 10.1016/0005-2787(77)90236-2.

DOI:10.1016/0005-2787(77)90236-2
PMID:884112
Abstract

An X-ray study of the crystal structure of a cobalt(II) complex with uridine 5'-monophosphate shows it to contain polymeric chains of composition [Co2(H2O)4 (5'-UMP)2]n. The cobalt atoms do not bind to the pyrimidine base moiety; instead each metal atom is octahedrally coordinated to four phosphate groups and two water molecules. Managanese(II) forms a similar compound.

摘要

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引用本文的文献

1
Cobalt(II), nickel(II) and zinc(II) do not bind to intra-helical N(7) guanine positions in the B-form crystal structure of d(GGCGCC).钴（II）、镍（II）和锌（II）不与d(GGCGCC)的B型晶体结构中螺旋内的鸟嘌呤N(7)位结合。
J Biol Inorg Chem. 2003 Sep;8(7):715-20. doi: 10.1007/s00775-003-0473-4. Epub 2003 Jul 9.
2
Zwitterionic character of nucleotides: possible significance in the evolution of nucleic acids.核苷酸的两性离子特性：在核酸进化中的可能意义。
Nucleic Acids Res. 1978 Nov;5(11):4375-83. doi: 10.1093/nar/5.11.4375.