Zhang D, Miyase T, Kuroyanagi M, Umehara K, Noguchi H
School of Pharmaceutical Sciences, University of Shizuoka, Japan.
Chem Pharm Bull (Tokyo). 1996 Nov;44(11):2092-9. doi: 10.1248/cpb.44.2092.
Nine new oleanane-type saponins, polygalasaponins XXXIII--XLI, along with seven known saponins were isolated from the roots of Polygala fallax HEMSL. Polygalasaponins XXXIII-XLI were elucidated as 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl- (1-->2)-(4-O-acetyl)-beta-D-fuco-pyranosyl ester, 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-galactopyranosyl-(1-->4)-beta-D-xylopyranosyl- (1-->4)-alpha-L-rhamnopyranosyl-(1-->2)-(4-O-acetyl)-beta-D- fucopyranosyl ester, 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-galactopyranosyl-(1-->4)-beta-D-xylopyranosyl-(1-->4)- alpha-L-rhamnopyranosyl-(1-->2)-(3,4-di-O-acetyl)-beta-D-fucopyranosyl ester, 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-galactopyranosyl-(1-->4)-beta-D-xylopyranosyl-(1-->4)- [(5-O-acetyl)-beta-D-apiofuranosyl-(1-->3)]-alpha-L-rhamnopyranosy l- (1-->2)-(3,4-di-O-acetyl)-beta-D-fucopyranosyl ester, 3-O-beta-D-glucopyranosyl-(1-->2)-beta-D-glucopyranosyl presenegenin 28-O-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl-(1-->2)- (3-O-acetyl)-beta-D-fucopyranosyl ester, 3-O-beta-D-glucopyranosyl- (1-->2)-beta-D-glucopyranosyl presenegenin 28-O-beta-D-galactopyranosyl-(1-->4)-beta-D-xylopyranosyl- (1-->4)-alpha-L-rhamnopyranosyl-(1-->2)-(4-O-acetyl)-beta-D- fucopyranosyl ester, 3-O-beta-D-glucopyranosyl-(1-->2)-beta-D-glucopyranosyl presenegenin 28-O-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl-(1-->2)- [alpha-L-rhamnopyranosyl-(1-->3)]-(4-O-acetyl)-beta-D-fucopyranosyl ester, 3-O-beta-D-glucopyranosyl-(1-->2)-beta-D-glucopyranosyl presenegenin 28-O-beta-D-galactopyranosyl-(1-->4)-beta-D-xylopyranosyl-(1-->4)- [beta-D-apiofuranosyl-(1-->3)]-alpha-L-rhamnopyranosyl-(1-->2)- (3,4-di-O-acetyl)-beta-D-fucopyranosyl ester and 3-O-beta-D-glucopyranosyl-(1-->2)-beta-D-glucopyranosyl presenegenin 28-O-beta-D-galactopyranosyl-(1-->4)-beta-D-xylopyranosyl-(1-->4)- [(5-O-acetyl)-beta-D-apiofuranosyl-(-->3)]-alpha-L-rhamnopyranosyl - (1-->2)-(3,4-di-O-acetyl)-beta-D-fucopyranosyl ester, respectively, on the basis of spectroscopic and chemical evidence.
从黄花倒水莲（Polygala fallax HEMSL.）根部分离得到9个新的齐墩果烷型皂苷，即远志皂苷XXXIII - XLI，以及7个已知皂苷。根据光谱和化学证据，确定远志皂苷XXXIII - XLI分别为3 - O - β - D - 吡喃葡萄糖基前远志皂苷元28 - O - β - D - 吡喃木糖基 - (1→4) - α - L - 吡喃鼠李糖基 - (1→2) - (4 - O - 乙酰基) - β - D - 岩藻糖基酯、3 - O - β - D - 吡喃葡萄糖基前远志皂苷元28 - O - β - D - 吡喃半乳糖基 - (1→4) - β - D - 吡喃木糖基 - (1→4) - α - L - 吡喃鼠李糖基 - (1→2) - (4 - O - 乙酰基) - β - D - 岩藻糖基酯、3 - O - β - D - 吡喃葡萄糖基前远志皂苷元28 - O - β - D - 吡喃半乳糖基 - (1→4) - β - D - 吡喃木糖基 - (1→4) - α - L - 吡喃鼠李糖基 - (1→2) - (3,4 - 二 - O - 乙酰基) - β - D - 岩藻糖基酯、3 - O - β - D - 吡喃葡萄糖基前远志皂苷元28 - O - β - D - 吡喃半乳糖基 - (1→4) - β - D - 吡喃木糖基 - (1→4) - [(5 - O - 乙酰基) - β - D - 阿吡喃糖基 - (1→3)] - α - L - 吡喃鼠李糖基 - (1→2) - (3,4 - 二 - O - 乙酰基) - β - D - 岩藻糖基酯、3 - O - β - D - 吡喃葡萄糖基 - (1→2) - β - D - 吡喃葡萄糖基前远志皂苷元28 - O - β - D - 吡喃木糖基 - (1→4) - α - L - 吡喃鼠李糖基 - (1→2) - (3 - O - 乙酰基) - β - D - 岩藻糖基酯、3 - O - β - D - 吡喃葡萄糖基 - (1→2) - β - D - 吡喃葡萄糖基前远志皂苷元28 - O - β - D - 吡喃半乳糖基 - (1→4) - β - D - 吡喃木糖基 - (1→4) - α - L - 吡喃鼠李糖基 - (1→2) - (
