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[植物天然及工艺变化香气的定量组成。II. 橙子中的香气化合物及其在果汁加工过程中的变化(作者译)]

[The quantitative composition of natural and technologically changed aromas of plants. II. Aroma compounds in oranges and their changes during juice processing (author's transl)].

作者信息

Schreier P, Drawert F, Junker A, Mick W

出版信息

Z Lebensm Unters Forsch. 1977 Jul 29;164(3):188-93. doi: 10.1007/BF01263029.

DOI:10.1007/BF01263029
PMID:910553
Abstract

After enzyme inhibition with methanol the original volatile compounds of the fruits were investigated in order to compare the quantitative composition of the aroma substances in orange fruits and juices. Aroma compounds of fresh, flash pasteurized and pasteurized juices were analysed. After aroma enrichment by liquid-liquid extraction, prefractionation of the flavor compounds by column chromatography on silicagel 56 flavor substances in the fruits and in the different juices were identified and determined by gas chromatography and mass spectrometry. In comparison to their content in the fruits only 10% of the terpenic hydrocarbons and about 30-66% of the esters were found on average in the fruits. Among the secondary flavor substances, which were not present or present only in traces in the fruits, but showed in juices concentrations up to 0,2 ppm, were 4-terpinenol, carveol and tr-2,8-menthadien-1-ol. After a thermic treatment also 3-hydroxy-2-butanone and 3-methyl-2-buten-1-ol were identified.

摘要

用甲醇抑制酶活性后,对水果中的原始挥发性化合物进行了研究,以便比较橙子果实和果汁中香气物质的定量组成。分析了新鲜果汁、瞬时巴氏杀菌果汁和巴氏杀菌果汁的香气成分。通过液液萃取进行香气富集后,通过硅胶柱色谱对风味化合物进行预分离,利用气相色谱和质谱法对果实和不同果汁中的56种风味物质进行了鉴定和测定。与果实中的含量相比,果实中平均仅发现10%的萜烯碳氢化合物和约30 - 66%的酯类。在次生风味物质中,4-萜品醇、香芹醇和反式-2,8-薄荷二烯-1-醇在果实中不存在或仅微量存在,但在果汁中的浓度高达0.2 ppm。经过热处理后,还鉴定出了3-羟基-2-丁酮和3-甲基-2-丁烯-1-醇。

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