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12CD3I和13CD3I的基本振动模式nu3和nu6的红外光谱分析

Analysis of the Infrared Spectra of the Fundamentals nu3 and nu6 of 12CD3I and 13CD3I.

作者信息

Koivusaari M

机构信息

Department of Physical Sciences, University of Oulu, Oulu, 90571, Finland

出版信息

J Mol Spectrosc. 1997 Sep;185(1):123-7. doi: 10.1006/jmsp.1997.7342.

DOI:10.1006/jmsp.1997.7342
PMID:9344802
Abstract

The high-resolution infrared spectra of the lowest fundamental bands nu3 and nu6 of 12CD3I and 13CD3I have been measured using a Fourier transform spectrometer. The bands are analyzed on one hand by taking into account the Coriolis resonance nu3/nu6 and on the other hand without this Coriolis effect. The molecular constants obtained for the two vibration modes are introduced and a discussion of the influence of the Coriolis interaction to the parameter set is shortly outlined. Copyright 1997 Academic Press. Copyright 1997Academic Press

摘要

使用傅里叶变换光谱仪测量了(^{12}CD_3I)和(^{13}CD_3I)最低基频带(\nu_3)和(\nu_6)的高分辨率红外光谱。一方面，考虑科里奥利共振(\nu_3/\nu_6)对这些谱带进行分析，另一方面，不考虑这种科里奥利效应进行分析。介绍了两种振动模式获得的分子常数，并简要概述了科里奥利相互作用对参数集的影响。版权所有1997年学术出版社。版权所有1997年学术出版社

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