Ulenikov ON, Onopenko GA, Tyabaeva NE, Alanko S, Koivusaari M, Anttila R
Laboratory of Molecular Spectroscopy, Physics Department, Tomsk State University, Tomsk, 634050, Russia
J Mol Spectrosc. 1997 Dec;186(2):293-313. doi: 10.1006/jmsp.1997.7431.
The high-resolution absorption spectrum of the CHD3 molecule has been measured on a Fourier transform spectrometer in the region of the nu5 and nu3/nu6 bands and analyzed for the first time by taking into account a1 - a2 (K = 3) splittings of the ground vibrational state. The problem of ambiguity in determining the corresponding epsilon; parameter of the ground vibrational state was solved on the basis of the analysis of the rotational structure of the nu5 band. Numerous a1-a2 splittings for the states with Kupper = 1, 2, 4, 5, 7 in the nu5 and nu6 bands are described. Copyright 1997 Academic Press. Copyright 1997Academic Press
已在傅里叶变换光谱仪上测量了CHD3分子在ν5和ν3/ν6带区域的高分辨率吸收光谱，并首次通过考虑基振动态的a1 - a2（K = 3）分裂进行了分析。基于对ν5带转动结构的分析，解决了确定基振动态相应ε参数时的模糊性问题。描述了ν5和ν6带中K上 = 1、2、4、5、7态的大量a1 - a2分裂。版权所有1997年学术出版社。版权所有1997年学术出版社
