Reduction of alkyl (2-oxocyclohexyl)acetates by baker's yeast.
作者信息
Ganaha M, Funabiki Y, Motoki M, Yamauchi S, Kinoshita Y
机构信息
Department of Agricultural Chemistry, Faculty of Agriculture, Ehime University, Matsuyama, Japan.
出版信息
Biosci Biotechnol Biochem. 1998 Jan;62(1):181-4. doi: 10.1271/bbb.62.181.
PMID:9501532
Abstract
Baker's yeast reduction of methyl and ethyl (2-oxocyclohexyl) acetates proceeded with enantio- and diastereo-selectivity, affording the corresponding (2S)-trans-alcohols (major), (2S)-cis-alcohols (minor), and the unaltered (1S)-ketones with high optical purity.
摘要
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