山姜素H、表山姜素H以及山姜叶素A和B，来自山姜叶山姜种子的新型二芳基庚烷类化合物。

Calyxin H, Epicalyxin H, and Blepharocalyxins A and B, Novel Diarylheptanoids from the Seeds of Alpinia blepharocalyx.

作者信息

Prasain JK, Li JX, Tezuka Y, Tanaka K, Basnet P, Dong H, Namba T, Kadota S

机构信息

Research Institute for Wakan-Yaku (Traditional Sino-Japanese Medicines), Toyama Medical and Pharmaceutical University, 2630-Sugitani, Toyama 930-01, Japan, National Research Institute of Police Science, 6 Sanban-cho, Chiyoda-Ku, Tokyo 102, Japan, and China Pharmaceutical University, 24 Tong Jia Xiang, Nanjing, People's Republic of China.

出版信息

J Nat Prod. 1998 Feb 27;61(2):212-6. doi: 10.1021/np970404d.

DOI:10.1021/np970404d

PMID:9548849

Abstract

Four unprecedented diarylheptanoids-calyxin H (1) and epicalyxin H (2), possessing a diarylheptanoid unit and a chalcone moiety, and blepharocalyxins A (3) and B (4), possessing two diarylheptanoid units and a chalcone moiety-were isolated from the seeds of Alpiniablepharocalyx. The structures of 1-4, including absolute stereochemistry, were elucidated by spectroscopic means and after a consideration of their biogenesis.

摘要

从毛萼山姜种子中分离出四种前所未有的二芳基庚烷类化合物——具有二芳基庚烷单元和查耳酮部分的卡里辛H（1）和表卡里辛H（2），以及具有两个二芳基庚烷单元和查耳酮部分的毛萼山姜素A（3）和B（4）。通过光谱手段并考虑其生源合成对1-4的结构（包括绝对立体化学）进行了阐明。