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氦的悖论

The helium paradoxes.

作者信息

Anderson D L

机构信息

Seismological Laboratory 252-21, California Institute of Technology, Pasadena, CA 91125, USA.

出版信息

Proc Natl Acad Sci U S A. 1998 Apr 28;95(9):4822-7. doi: 10.1073/pnas.95.9.4822.

Abstract

The ratio 3He/4He (R) plays a central role in models of mantle evolution that propose an undegassed lower mantle, rich in the primordial isotope 3He. A large primordial volatile-rich reservoir, a feature of recent models, is inconsistent with high-temperature accretion and with estimates of crustal and bulk Earth chemistry. High R can alternatively reflect high integrated 3He/(U+Th) ratios or low 4He abundances, as expected in refractory portions of the upper mantle. I show that high R materials are gas-poor and are deficient in radiogenic 4He compared with midocean ridge basalts. The seemingly primitive (i.e., high R) signatures in "hotspot" magmas may be secondary, derived from CO2-rich gases, or residual peridotite, a result of differential partitioning of U and He into magmas. A shallow and low 3He source explains the spatial variability and the temporal trends of R in ocean islands and is consistent with a volatile-poor planet. A shallow origin for the "primitive" He signature in ocean island basalts, such as at Loihi, reconciles the paradoxical juxtaposition of crustal, seawater, and atmospheric signatures with inferred "primitive" characteristics. High 238U/204Pb components in ocean island basalts are generally attributed to recycled altered oceanic crust. The low 238U/3He component may be in the associated depleted refractory mantle. High 3He/4He ratios are due to low 4He, not excess 3He, and do not imply or require a deep or primordial or undegassed reservoir. 40Ar in the atmosphere also argues against such models.

摘要

3He/4He 比值(R)在提出下地幔未脱气且富含原始同位素 3He 的地幔演化模型中起着核心作用。近期模型所具有的一个大型富含挥发性物质的原始储库,与高温吸积以及地壳和地球整体化学的估计值不一致。相反,高 R 值可能反映了上地幔难熔部分预期的高积分 3He/(U + Th) 比值或低 4He 丰度。我表明,与大洋中脊玄武岩相比,高 R 值物质贫气且缺乏放射性 4He。“热点”岩浆中看似原始(即高 R)的特征可能是次生的,源自富含 CO2 的气体或残余橄榄岩,这是 U 和 He 向岩浆中差异分配的结果。一个浅部且低 3He 的源可以解释海洋岛屿中 R 的空间变异性和时间趋势,并且与贫挥发分的行星相一致。海洋岛屿玄武岩中“原始”He 特征的浅部起源,比如在罗希海底山,调和了地壳、海水和大气特征与推断的“原始”特征之间看似矛盾的并列关系。海洋岛屿玄武岩中高 238U/204Pb 成分通常归因于再循环的蚀变洋壳。低 238U/3He 成分可能存在于相关的亏损难熔地幔中。高 3He/4He 比值是由于低 4He,而非过量的 3He,并且并不意味着或需要一个深部、原始或未脱气的储库。大气中的 40Ar 也与这类模型相悖。

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