Liu J, Rinzler AG, Dai H, Hafner JH, Bradley RK, Boul PJ, Lu A, Iverson T, Shelimov K, Huffman CB, Rodriguez-Macias F, Shon YS, Lee TR, Colbert DT, Smalley RE
J. Liu, A. G. Rinzler, H. Dai, J. H. Hafner, R. K. Bradley, P. J. Boul, A. Lu, T. Iverson, K. Shelimov, C. B. Huffman, F. Rodriguez-Macias, D. T. Colbert, R. E. Smalley, Center for Nanoscale Science and Technology, Rice Quantum Institute.
Science. 1998 May 22;280(5367):1253-6. doi: 10.1126/science.280.5367.1253.
Single-wall fullerene nanotubes were converted from nearly endless, highly tangled ropes into short, open-ended pipes that behave as individual macromolecules. Raw nanotube material was purified in large batches, and the ropes were cut into 100- to 300-nanometer lengths. The resulting pieces formed a stable colloidal suspension in water with the help of surfactants. These suspensions permit a variety of manipulations, such as sorting by length, derivatization, and tethering to gold surfaces.
单壁富勒烯纳米管从几乎无限长、高度缠结的绳索状转变为短的、开口的管状物,其表现如同单个大分子。原始纳米管材料被大批量纯化,绳索状纳米管被切割成100至300纳米长的片段。借助表面活性剂,这些片段在水中形成了稳定的胶体悬浮液。这些悬浮液允许进行各种操作,例如按长度分类、衍生化以及连接到金表面。