Hammarling L, Gustavsson H, Svensson K, Karlsson S, Oskarsson A
National Food Administration, Uppsala, Sweden.
Food Addit Contam. 1998 Feb-Mar;15(2):203-8. doi: 10.1080/02652039809374631.
Expoxidized soya bean oil (ESBO) is used as a plasticizer in PVC gaskets in lids for glass jars used for packaging of ready-cooked baby food. The migration of ESBO from the lids has been determined in 81 samples of different dishes of baby food, including purées of beef, pork, fish, poultry, berries and vegetables. The level of ESBO in baby food has been determined using a gas chromatography/mass spectrometry (GC/MS) analytical procedure with a detection limit of 1.5 mg/kg. Residues of ESBO were found in all dishes except in blueberries. The levels ranged from < 1.5 to 50.8 mg/kg, with a mean of 11.9 mg/kg and a median of 7.8 mg/kg in food with detectable levels. Expoxidized fatty acids may also occur naturally in food. Baby food which had never been in contact with the lids was therefore analysed and no detectable levels of diepoxidized C18-methylester, which was used for the determination of ESBO, were found. That demonstrates that the presented levels of ESBO in the baby food are only due to migration from the lids and not of natural origin.
环氧大豆油(ESBO)被用作玻璃罐盖子中PVC垫片的增塑剂,这些玻璃罐用于包装即食婴儿食品。已在81份不同种类的婴儿食品样本中测定了ESBO从盖子中的迁移情况,这些样本包括牛肉、猪肉、鱼肉、禽肉、浆果和蔬菜泥。采用气相色谱/质谱联用(GC/MS)分析方法测定婴儿食品中的ESBO含量,检测限为1.5毫克/千克。除蓝莓外,在所有食品中均发现了ESBO残留。含量范围为<1.5至50.8毫克/千克,在可检测到ESBO的食品中,平均含量为11.9毫克/千克,中位数为7.8毫克/千克。环氧脂肪酸也可能天然存在于食品中。因此,对从未接触过盖子的婴儿食品进行了分析,未发现用于测定ESBO的二环氧C18 -甲酯的可检测水平。这表明婴儿食品中ESBO的含量仅源于从盖子中的迁移,而非天然来源。