• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

[一种了解仪器测量统计可靠性的方法]

[A method for knowing the statistical reliability of instrumental measurements].

作者信息

Hayashi Y, Matsuda R

出版信息

Kokuritsu Iyakuhin Shokuhin Eisei Kenkyusho Hokoku. 1997(115):206-7.

PMID:9641847
Abstract

The precision of instrumental measurements, usually expressed by SD (standard deviation) or RSD (relative standard deviation) is of importance in a society as well as in a world of analytical chemistry. For example, the detection limit and confidence intervals of calibration lines which are based on the precision are inevitable for regulatory science. As is well-known in statistics, however, a small number of repetitive experiments (e.g., 5) lead to a poor reliability of the precision. This presentation shows a method (called FUMI theory) which can provide a precision from a single measurement of noise and signal without any repetitive measurements. The statistical reliability of the precision from the FUMI theory corresponds to that from the repetitive method of 50 experiments.

摘要

仪器测量的精度通常用标准差(SD)或相对标准偏差(RSD)来表示,这在社会以及分析化学领域都很重要。例如,基于精度的校准曲线的检测限和置信区间对于监管科学来说是不可避免的。然而,正如统计学中所熟知的那样,少量的重复实验(例如5次)会导致精度的可靠性较差。本报告展示了一种方法(称为FUMI理论),该方法无需任何重复测量,仅通过单次测量噪声和信号就能提供精度。FUMI理论得出的精度的统计可靠性与50次实验的重复方法得出的相当。

相似文献

1
[A method for knowing the statistical reliability of instrumental measurements].[一种了解仪器测量统计可靠性的方法]
Kokuritsu Iyakuhin Shokuhin Eisei Kenkyusho Hokoku. 1997(115):206-7.
2
[Relationship between design of calibration and precision of measurement].校准设计与测量精度之间的关系
Kokuritsu Iyakuhin Shokuhin Eisei Kenkyusho Hokoku. 1997(115):208-9.
3
Theoretical repeatability assessment without repetitive measurements in gradient high-performance liquid chromatography.
J Chromatogr A. 2016 Jul 8;1454:26-31. doi: 10.1016/j.chroma.2016.05.065. Epub 2016 May 20.
4
Validation of HPLC and GC-MS systems for bisphenol-A leached from hemodialyzers on the basis of FUMI theory.
J Pharm Biomed Anal. 2002 May 15;28(3-4):421-9. doi: 10.1016/s0731-7085(01)00698-7.
5
Precision, limit of detection and range of quantitation in competitive ELISA.竞争酶联免疫吸附测定中的精密度、检测限和定量范围
Anal Chem. 2004 Mar 1;76(5):1295-301. doi: 10.1021/ac0302859.
6
Precision and detection limit of quality test for amorphous drug in powder X-ray diffractometry.
Int J Pharm. 2004 Sep 28;283(1-2):63-9. doi: 10.1016/j.ijpharm.2004.06.024.
7
Chemometric evaluations of repeatability and detection limit in high-performance liquid chromatography with electrochemical detection.高效液相色谱电化学检测中的重复性和检测限的化学计量学评估。
J Chromatogr A. 2022 Jun 21;1673:463075. doi: 10.1016/j.chroma.2022.463075. Epub 2022 Apr 17.
8
Prediction of measurement precision of apparatus using a chemometric tool in electrochemical detection of high-performance liquid chromatography.
J Chromatogr A. 2003 Feb 7;986(2):239-46. doi: 10.1016/s0021-9673(02)02009-5.
9
Statistical and probabilistic approaches to confidence intervals of linear calibration in liquid chromatography.液相色谱中线性校准置信区间的统计与概率方法
Analyst. 2001 Nov;126(11):2061-5. doi: 10.1039/b105325f.
10
Analysis of compound weighing precision in drug discovery.药物研发中化合物称量精度的分析
J Biomol Screen. 2013 Mar;18(3):331-40. doi: 10.1177/1087057112461152. Epub 2012 Sep 26.