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碳纤维的阳极表面处理:复合体系中两个不同固体表面之间酸碱相互作用参数的测定

Anodic Surface Treatment on Carbon Fibers: Determination of Acid-Base Interaction Parameter between Two Unidentical Solid Surfaces in a Composite System.

作者信息

Park SJ, Donnet JB

机构信息

Advanced Materials Division, Korea Research Institute of Chemical Technology, Yusong, Taejon, 305-600, Korea

出版信息

J Colloid Interface Sci. 1998 Oct 1;206(1):29-32. doi: 10.1006/jcis.1998.5672.

DOI:10.1006/jcis.1998.5672
PMID:9761624
Abstract

An interpretation based on more precise linear free energy relationships is proposed for the determination of the acid-base interaction of a solid surface, in the context of inverse gas chromatography at infinite dilution. This work leads to the evaluation of acid-base interaction parameter, Ia-b, between two constitutive elements in a composite system. In this work, the acid-base interaction parameters between fibers and matrix are greatly correlated with the results of the interfacial shear strength carried out on single fibers and the interlaminar shear strength of the composites. As an experimental result, electrochemical treatment of fiber surfaces significantly appears essential to the improvement of the acid-base character in a way expected from the nature of the electrolytes used during the treatment. Copyright 1998 Academic Press.

摘要

在无限稀释反相气相色谱的背景下,提出了一种基于更精确线性自由能关系的解释,用于确定固体表面的酸碱相互作用。这项工作得出了复合体系中两个组成元素之间酸碱相互作用参数Ia-b的评估结果。在这项工作中,纤维与基体之间的酸碱相互作用参数与单纤维界面剪切强度和复合材料层间剪切强度的结果密切相关。作为实验结果,纤维表面的电化学处理对于以处理过程中所用电解质性质所预期的方式改善酸碱特性显得至关重要。版权所有1998年,学术出版社。

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