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γ 辐照红宝石晶体中杂质核自旋 - 晶格弛豫抑制及铬离子的电荷交换

Impurity nuclear spin-lattice relaxation suppression and charge exchange of chromium ions in a gamma-irradiated ruby crystal.

作者信息

Chandoul A, Charnaya E V, Kuleshov A A, Mikushev V M, Ulyashev A M

机构信息

Institute of Physics, St. Petersburg State University, St. Petersburg, 198904, Russia.

出版信息

J Magn Reson. 1998 Nov;135(1):113-7. doi: 10.1006/jmre.1998.1550.

Abstract

The possibility of directly separating and measuring the impurity and lattice contributions to nuclear spin-lattice relaxation under the condition of a steady-state magnetic saturation is demonstrated in the particular case of 27Al nuclei in a gamma-irradiated ruby crystal. Contributions from trivalent and charge-exchanged chromium ions to impurity nuclear relaxation were separated. The number of charge-exchanged chromium ions was found. The spin relaxation time of Cr4+ centers was estimated.

摘要

在γ辐照红宝石晶体中27Al核的特定情况下,证明了在稳态磁饱和条件下直接分离并测量杂质和晶格对核自旋 - 晶格弛豫贡献的可能性。分离了三价和电荷交换铬离子对杂质核弛豫的贡献。确定了电荷交换铬离子的数量。估计了Cr4+中心的自旋弛豫时间。

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