磷玻璃中31P核磁共振化学位移张量主值的分布
Distribution of principal values of the 31P NMR chemical shift tensor in phosphate glasses.
作者信息
Losso P, Sternberg U
机构信息
Institut für Optik und Quantenelektronik, Friedrich-Schiller-Universität Jena, Germany.
出版信息
Solid State Nucl Magn Reson. 1998 Nov;13(1-2):113-8. doi: 10.1016/s0926-2040(98)00064-2.
The static line shapes of the powder pattern of the 31P nuclear magnetic resonance (NMR) chemical shift (CS) tensor in phosphate glasses can only be explained by using individual distributions parameters for the principal axes. A model is discussed, which assumes a linear dependency of such distributions from the principal values themselves. Furthermore, the influence of such distributions on magic angle spinning (MAS) spectra is investigated.
磷酸盐玻璃中31P核磁共振（NMR）化学位移（CS）张量粉末图谱的静态线形，只能通过使用主轴的单独分布参数来解释。本文讨论了一个模型，该模型假设这些分布与主值本身存在线性相关性。此外，还研究了这些分布对魔角旋转（MAS）光谱的影响。
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