Ong K K, Fakhru'l-Razi A, Baharin B S, Hassan M A
Department of Chemical and Environmental Engineering, Universiti Putra Malaysia, Selangor.
Artif Cells Blood Substit Immobil Biotechnol. 1999 Sep-Nov;27(5-6):381-5. doi: 10.3109/10731199909117707.
The application of membrane separation in palm oil refining process has potential for energy and cost savings. The conventional refining of crude palm oil results in loss of oil and a contaminated effluent. Degumming of crude palm oil by membrane technology is conducted in this study. The objective of this research is to study the feasibility of membrane filtration for the removal of phospholipids in the degumming of crude palm oil, including analyses of phosphorus content, carotene content free fatty acids (as palmitic acid), colour and volatile matter. A PCI membrane module was used which was equipped with polyethersulfone membranes having a molecular weight cut off of 9,000 (type ES209). In this study, phosphorus content was the most important parameter monitored. The membrane effectively removed phospholipids resulting in a permeate with a phosphorus content of less than 0.3 ppm The percentage removal of phosphorus was 96.4% and was considered as a good removal. Lovibond colour was reduced from 27R 50Y to 20R 30Y. The percentage removal of carotene was 15.8%. The removal of colour was considered good but the removal of carotene was considered insignificant by the membrane. Free fatty acids and volatile matter were not removed. Typical of membrane operations, the permeate flux decreased with time and must be improved in order to be adopted on an industrial scale. Membrane technology was found to have good potential in crude palm oil degumming. However, an appropriate method has to be developed to clean the membranes for reuse.
膜分离技术在棕榈油精炼过程中的应用具有节能和降低成本的潜力。传统的粗棕榈油精炼会导致油脂损失和废水污染。本研究采用膜技术对粗棕榈油进行脱胶。本研究的目的是探讨膜过滤法去除粗棕榈油脱胶过程中磷脂的可行性,包括对磷含量、胡萝卜素含量、游离脂肪酸(以棕榈酸计)、色泽和挥发性物质的分析。使用了一个PCI膜组件,其配备了截留分子量为9000的聚醚砜膜(ES209型)。在本研究中,磷含量是监测的最重要参数。该膜有效地去除了磷脂,使得透过液中的磷含量低于0.3 ppm,磷的去除率为96.4%,被认为是良好的去除效果。罗维朋色泽从27R 50Y降至20R 30Y。胡萝卜素的去除率为15.8%。膜对色泽的去除效果良好,但对胡萝卜素的去除效果不显著。游离脂肪酸和挥发性物质未被去除。与典型的膜操作一样,透过通量随时间下降,为了在工业规模上应用,必须加以改进。研究发现,膜技术在粗棕榈油脱胶方面具有良好的潜力。然而,必须开发一种合适的方法来清洗膜以便重复使用。