Bora U, Bose G, Chaudhuri MK, Dhar SS, Gopinath R, Khan AT, Patel BK
Department of Chemistry, Indian Institute of Technology, Guwahati.
Org Lett. 2000 Feb 10;2(3):247-9. doi: 10.1021/ol9902935.
[reaction: see text] Vanadium pentoxide very effectively promotes the bromination of organic substrates, including selective bromination of some aromatics, by tetrabutylammonium bromide in the presence of hydrogen peroxide; mild conditions, high selectivity, yield, and reaction rate, and redundancy of bromine and hydrobromic acid are some of the major advantages of the synthetic protocol.
[反应:见正文] 在过氧化氢存在下,五氧化二钒能非常有效地促进有机底物的溴化反应,包括某些芳烃的选择性溴化反应;温和的条件、高选择性、高收率和高反应速率,以及溴和氢溴酸的冗余性是该合成方法的一些主要优点。