可见光光氧化还原催化实现了酚和烯烃的溴化反应。
Visible-light photoredox catalysis enabled bromination of phenols and alkenes.
机构信息
State Key Lab of Urban Water Resource and Environment, The Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China.
出版信息
Beilstein J Org Chem. 2014 Mar 7;10:622-7. doi: 10.3762/bjoc.10.53. eCollection 2014.
Abstract
A mild and efficient methodology for the bromination of phenols and alkenes has been developed utilizing visible light-induced photoredox catalysis. The bromine was generated in situ from the oxidation of Br(-) by Ru(bpy)3 (3+), both of which resulted from the oxidative quenching process.
摘要
一种温和、高效的酚类和烯烃溴化方法已经开发出来，利用可见光诱导的光氧化还原催化作用。溴是由 Ru(bpy)3(3+)氧化 Br(-)原位生成的，这两种物质都是氧化猝灭过程的结果。
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