Belaj F, Basch A, Muster U
Institut fur Chemie, Karl-Franzens-Universitat Graz, Schubertstrasse 1, A-8010 Graz, Austria. ferdinand.belaj@kfunigraz. ac.at.
Acta Crystallogr C. 2000 Aug;56 (Pt 8):921-2. doi: 10.1107/s0108270100006491.
In the structure of the title compound, [VO(C(2)O(4))(H(2)O)(3)]. 2H(2)O, the V atom of the oxovanadium(IV) cation is coordinated to one bidentate oxalate anion and three water molecules, resulting in a neutral complex. Two more water molecules are not coordinated to the V atoms but are involved in the hydrogen-bonding network, which consists of ten different hydrogen bonds.
在标题化合物[VO(C₂O₄)(H₂O)₃]·2H₂O的结构中,氧钒(IV)阳离子的钒原子与一个双齿草酸根阴离子和三个水分子配位,形成一个中性配合物。另外两个水分子不与钒原子配位,但参与了氢键网络,该氢键网络由十种不同的氢键组成。