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[N,N'-双(3-羧基水杨醛)-1,2-二苯基-(RR,SS)-1,2-乙二胺基-O,N,N',O'](甲醇-O)氧钒(IV)和[N,N'-双(3-羧基水杨醛)-2,3-二甲基-2,3-丁二胺基-O,N,N',O']氧钒(IV)一水合物

[N,N'-Bis(3-carboxysalicylidene)-1,2-diphenyl-(RR,SS)-1,2-ethanediyldiaminato-O,N,N',O'](methanol-O)oxovanadium(IV) and [N,N'-bis(3-carboxysalicylidene)-2,3-dimethyl-2,3-butanediyldiaminato-O,N,N',O']oxovanadium(IV) monohydrate.

作者信息

Uemura R, Tsuchimoto M, Ohba S

机构信息

Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan.

出版信息

Acta Crystallogr C. 2000 May 15;56(Pt 5):E199-200. doi: 10.1107/S0108270100005679.

DOI:10.1107/S0108270100005679
PMID:15263149
Abstract

The two title mononuclear oxovanadium (IV) complexes, [VO(C(30)H(22)N(2)O(6))(CH(3)OH)] and [VO(C(22)H(22)N(2)O(6))].H(2)O, respectively, have distorted square-pyramidal coordination and the 3-carboxy groups form intramolecular hydrogen bonds with the coordinated salicyl O atoms. In (I), methanol coordinates to the vanadium atom trans with respect to the oxo ligand.

摘要

两个标题单核氧钒（IV）配合物，分别为[VO(C₃₀H₂₂N₂O₆)(CH₃OH)]和[VO(C₂₂H₂₂N₂O₆)].H₂O，具有扭曲的四方锥配位结构，且3-羧基与配位的水杨基O原子形成分子内氢键。在（I）中，甲醇相对于氧代配体以反式方式与钒原子配位。

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