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琼脂糖凝胶弹性浓度依赖性的标度分析

Scaling analysis of the concentration dependence on elasticity of agarose gel.

作者信息

Fujii T, Yano T, Kumagai H, Miyawaki O

机构信息

Department of Applied Biological Chemistry, The University of Tokyo, Japan.

出版信息

Biosci Biotechnol Biochem. 2000 Aug;64(8):1618-22. doi: 10.1271/bbb.64.1618.

Abstract

Since the critical exponent of the elastic modulus is related to the spatial dimension and the critical exponent of the correlation length, depending on the characteristics of elasticity, we experimentally evaluated both the elastic modulus of a sol-gel transition system and also the correlation length. We could determine the correlation length of agarose gel by the dynamic light scattering method; it was well described by the power law as a function of the deviation from the sol-gel transition point. Three scaling laws between the critical exponent of the correlation length (v) and that of the elastic shear modulus (t) were compared, and the critical exponent of the elastic modulus was described by the equation of de Gennes expression (t=1+v(d-2), where d is the spatial dimension). This result suggests that agarose fibers are stiff enough to show scalar elasticity.

摘要

由于弹性模量的临界指数与空间维度以及关联长度的临界指数相关,取决于弹性特征,我们通过实验评估了溶胶-凝胶转变体系的弹性模量以及关联长度。我们可以通过动态光散射法确定琼脂糖凝胶的关联长度;它可以用幂律很好地描述为偏离溶胶-凝胶转变点的函数。比较了关联长度的临界指数(ν)和弹性剪切模量的临界指数(τ)之间的三个标度律,并且弹性模量的临界指数由德热纳表达式(τ = 1 + ν(d - 2),其中d是空间维度)描述。该结果表明琼脂糖纤维足够硬以表现出标量弹性。

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