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磷酸钙与羟丙基甲基纤维素(HPMC)在有机/无机复合材料中是否存在化学相互作用?

Is there a chemical interaction between calcium phosphates and hydroxypropylmethylcellulose (HPMC) in organic/inorganic composites?

作者信息

Dorozhkin S V

机构信息

Research Institute of Fertilizers, Kudrinskaja sq. 1 - 155, 123242 Moscow D-242, Russia.

出版信息

J Biomed Mater Res. 2001 Feb;54(2):247-55. doi: 10.1002/1097-4636(200102)54:2<247::aid-jbm12>3.0.co;2-g.

Abstract

Solid composites of calcium phosphates and hydroxypropylmethylcellulose (HPMC) were prepared at temperatures of 121 degrees C. Three biologically relevant calcium phosphates were studied: CaHPO(4). 2H(2)O (DCPD), calcium deficient apatite (CDA), and biphasic calcium phosphate (BCP). Properties of the solid composites obtained were studied with FTIR, X-ray diffraction, and SEM techniques. Special attention was devoted to seeking a possible chemical interaction between calcium phosphates and HPMC. No interaction was found. Thus, HPMC was proven to have no influence on chemical properties of calcium phosphates.

摘要

在121摄氏度的温度下制备了磷酸钙与羟丙基甲基纤维素(HPMC)的固体复合材料。研究了三种具有生物学相关性的磷酸钙:磷酸二氢钙二水合物(DCPD)、缺钙磷灰石(CDA)和双相磷酸钙(BCP)。利用傅里叶变换红外光谱(FTIR)、X射线衍射和扫描电子显微镜(SEM)技术研究了所得固体复合材料的性能。特别关注了寻找磷酸钙与HPMC之间可能的化学相互作用。未发现相互作用。因此,证明HPMC对磷酸钙的化学性质没有影响。

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