Saikawa Y, Watanabe T, Hashimoto K, Nakata M
Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Yokohama, Japan.
Phytochemistry. 2000 Oct;55(3):237-40. doi: 10.1016/s0031-9422(00)00282-x.
The S absolute configuration of both chiral centers of xylindein was assigned using X-ray crystallographic heavy atom analysis after its conversion to a synthetic derivative. Crystallographic analysis of xylindein crystallized with phenols revealed that the proposed structure is the proper tautomer in the crystals.
将木林菌素转化为合成衍生物后,通过X射线晶体学重原子分析确定了其两个手性中心的S绝对构型。对与酚类一起结晶的木林菌素进行晶体学分析表明,所提出的结构是晶体中合适的互变异构体。