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印度枳椇(Aegle marmelos)胶的分级水解研究。

Graded-hydrolysis studies on bael (Aegle marmelos) gum.

作者信息

Roy A, Mukherjee A K, Rao C V

出版信息

Carbohydr Res. 1975 May;41:219-26. doi: 10.1016/s0008-6215(00)87020-2.

DOI:10.1016/s0008-6215(00)87020-2
PMID:1137837
Abstract

Graded hydrolysis of purified bael gum afforded three neutral and two acidic oligosaccharides, together with monosaccharides. These sugars were identified through periodate oxidation, methylation, reduction with lithium aluminum hydride, co-chromatography, and preparation of crystalline derivatives. The neutral oligosaccharides were characterized as 3-0-beta-D-galactopyranosyl-L-arabinose, 5-0-beta-D-galactopyranosyl-L-arabinose, and 3-0-beta-D-galactopyranosyl-D-galactose, and the acidic oligosaccharides as 3-0-(beta-D-galactopyranosyluronic acid)-D-galactose and 3-0-(beta-D-galactopyranosyluronic acid)-3-0-beta-D-galactopyranosyl-D-galactose.

摘要

对纯化的贝耳胶进行分级水解,得到了三种中性寡糖、两种酸性寡糖以及单糖。这些糖类通过高碘酸盐氧化、甲基化、用氢化铝锂还原、共色谱分析以及结晶衍生物的制备得以鉴定。中性寡糖的特征为3-O-β-D-吡喃半乳糖基-L-阿拉伯糖、5-O-β-D-吡喃半乳糖基-L-阿拉伯糖和3-O-β-D-吡喃半乳糖基-D-半乳糖,酸性寡糖的特征为3-O-(β-D-吡喃半乳糖醛酸)-D-半乳糖和3-O-(β-D-吡喃半乳糖醛酸)-3-O-β-D-吡喃半乳糖基-D-半乳糖。

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