基于环糊精的分子机器

Cyclodextrin-based molecular machines.

作者信息

Harada A

机构信息

Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

出版信息

Acc Chem Res. 2001 Jun;34(6):456-64. doi: 10.1021/ar000174l.

DOI:10.1021/ar000174l

PMID:11412082

Abstract

Cyclodextrins have been used as a cyclic component in the construction of supramolecular architectures. Recently they have been studied as a component in the construction of rotaxanes and catenanes. A cyclodextrin ring can translocate in some rotaxane and catenane structures. Therefore, much attention has been given to cyclodextrins as a component of molecular shuttles, motors, and machines. Attempts to design and synthesize molecular-level machines using cyclodextrins as a cyclic component are described.

摘要

环糊精已被用作超分子结构构建中的环状组分。最近，它们被研究作为轮烷和索烃构建中的一个组分。环糊精环可以在一些轮烷和索烃结构中移动。因此，环糊精作为分子穿梭体、分子马达和分子机器的一个组分受到了广泛关注。本文描述了以环糊精作为环状组分来设计和合成分子水平机器的尝试。