Hayashi N, Kobayashi Y, Kishi Y
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Org Lett. 2001 Jul 12;3(14):2249-52. doi: 10.1021/ol010109r.
[structure: see text] Three additional NMR databases, 1-3, in a chiral solvent are presented. The C.21-C.38 portion of oasomycin A is used to demonstrate the scope and limitation of the universal NMR database approach in a chiral solvent for assignment of relative and absolute stereochemistry without degradation and/or derivatization.
[结构:见正文] 本文展示了在手性溶剂中的另外三个核磁共振数据库1 - 3。稻瘟霉素A的C.21 - C.38部分用于证明通用核磁共振数据库方法在手性溶剂中用于确定相对和绝对立体化学而无需降解和/或衍生化的范围和局限性。