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迈向手性溶剂中核磁共振数据库的创建：用于确定无环仲醇绝对构型的双齿手性核磁共振溶剂

Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.

作者信息

Kobayashi Yoshihisa, Hayashi Nobuyuki, Kishi Yoshito

机构信息

Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, USA.

出版信息

Org Lett. 2002 Feb 7;4(3):411-4. doi: 10.1021/ol0171160.

DOI:10.1021/ol0171160
PMID:11820892
Abstract

The absolute configuration of acyclic secondary alcohols can be established from analysis of the chemical shift behaviors of the adjacent carbons in bidentate chiral solvents (R,R)- and (S,S)-1d as formulated in the boxed illustration.

摘要

无环仲醇的绝对构型可以通过分析如盒装插图中所示的在双齿手性溶剂(R,R)-和(S,S)-1d中相邻碳的化学位移行为来确定。

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Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.迈向手性溶剂中核磁共振数据库的创建：用于确定无环仲醇绝对构型的双齿手性核磁共振溶剂
Org Lett. 2002 Feb 7;4(3):411-4. doi: 10.1021/ol0171160.
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