Volkov A G, Gugeshashvili M I, Deamer D W
Department of Chemistry, University of California, Santa Cruz 95064, USA.
Electrochim Acta. 1995;40(18):2849-68. doi: 10.1016/0013-4686(95)00214-y.
This chapter focuses on multielectron reactions in organized assemblies of molecules at the liquid/liquid interface. We describe the thermodynamic and kinetic parameters of such reactions, including the structure of the reaction centers, charge movement along the electron transfer pathways, and the role of electric double layers in artificial photosynthesis. Some examples of artificial photosynthesis at the oil/water interface are considered, including water photooxidation to the molecular oxygen, oxygen photoreduction, photosynthesis of amphiphilic compounds and proton evolution by photochemical processes.
本章重点关注分子有序组装体在液/液界面处的多电子反应。我们描述了此类反应的热力学和动力学参数，包括反应中心的结构、电荷沿电子转移途径的移动，以及双电层在人工光合作用中的作用。还考虑了油/水界面处人工光合作用的一些实例，包括水光氧化生成分子氧、氧的光还原、两亲性化合物的光合作用以及光化学过程中的质子释放。
