Tan X, Wang F, Bi Y, He J, Su Y, Braeckman L, de Bacquer D, Vanhoorne M
Dept. of Public Health, Faculty of Medicine, Wuhan University, Wuhan 430071, P. R. of China.
Int J Hyg Environ Health. 2001 Jul;203(5-6):465-71. doi: 10.1078/1438-4639-00055.
Carbon disulfide is a well-known occupational hazard in the viscose industry, and studies have shown considerable health effects when workers are exposed to high concentrations of this reagent. At exposure levels below the TLV-TWA(31 mg/m3), findings remain contradictory, probably due to deficient exposure data. The present study tries to identify the occupational hazards and thoroughly assess the exposure levels in a Chinese viscose rayon plant.
An industrial hygienic field survey and a sampling campaign were carried out, including multi-gas monitoring, on-line measurements, and stationary assessment in the spinning hall as well as personal exposure sampling for spinners (by charcoal tube absorbing and GC-FPD analysis). All data was introduced into Foxpro database, and analyzed by Epi info (6.04) and SPSS.
On-line measurement showed that the geometric mean (GM) of carbon disulfide exposure amounted to 12.73 mg/m3 in 'exposure' and 0.08 mg/m3 in 'non-exposure' worksites. These concentrations in the air were related to the subject's activities showing the highest levels when they had to open the shield windows of the spinning machines. Stationary exposure measurements of carbon disulfide in the spinning hall amounted to 23.29 mg/m3 GM (range 5.8-97.94 mg/m3). Personal exposure of spinners was about 17.3 mg/m3 GM. Comparing these methods, the personal exposure sampling could exactly express the exposure levels of the worker's contacting situation. The on-line measurement by multi-gas monitor might also be recommended to the factory as it has its own advantages of rapid and independent assessment, but it under-estimates the exposure level.
二硫化碳是粘胶行业中一种众所周知的职业危害因素,研究表明,当工人暴露于高浓度的这种试剂时,会对健康产生相当大的影响。在低于时间加权平均阈限值(31毫克/立方米)的暴露水平下,研究结果仍然相互矛盾,这可能是由于暴露数据不足所致。本研究试图确定一家中国粘胶人造丝工厂中的职业危害因素,并全面评估暴露水平。
开展了一项工业卫生现场调查和采样活动,包括多气体监测、在线测量以及在纺纱车间进行的固定评估,同时对纺纱工进行个人暴露采样(采用活性炭管吸附和气相色谱 - 火焰光度检测分析)。所有数据都录入到Foxpro数据库中,并通过Epi info(6.04)和SPSS进行分析。
在线测量显示,“暴露”工作场所中二硫化碳暴露的几何均值(GM)为12.73毫克/立方米,“非暴露”工作场所为0.08毫克/立方米。空气中的这些浓度与工人的活动有关,当他们必须打开纺纱机的防护窗时浓度最高。纺纱车间中二硫化碳的固定暴露测量结果为几何均值23.29毫克/立方米(范围为5.8 - 97.94毫克/立方米)。纺纱工的个人暴露约为几何均值17.3毫克/立方米。比较这些方法,个人暴露采样能够准确表达工人接触情况下的暴露水平。多气体监测仪的在线测量也因其具有快速和独立评估的优点而可能被推荐给工厂,但它低估了暴露水平。