具有功能核心的树枝状大分子的超分子化学。
Supramolecular chemistry of dendrimers with functional cores.
作者信息
Diederich François, Felber Béatrice
机构信息
Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule-Hönggerberg, HCI, CH-8093 Zürich, Switzerland.
出版信息
Proc Natl Acad Sci U S A. 2002 Apr 16;99(8):4778-81. doi: 10.1073/pnas.052568099. Epub 2002 Mar 12.
Abstract
Dendritic microenvironments are analogous to local environments created within protein superstructures. Correspondingly, properties of functional cores such as molecular recognition and catalytic activity are profoundly influenced by the surrounding dendritic branches.
摘要
树枝状微环境类似于在蛋白质超结构中形成的局部环境。相应地，功能核心的特性，如分子识别和催化活性，会受到周围树枝状分支的深刻影响。
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本文引用的文献
1
A Large Dendritic Multiporphyrin Array as a Mimic of the Bacterial Light-Harvesting Antenna Complex: Molecular Design of an Efficient Energy Funnel for Visible Photons.一种作为细菌光捕获天线复合体模拟物的大型树枝状多卟啉阵列：用于可见光子的高效能量漏斗的分子设计。
Angew Chem Int Ed Engl. 2001 Sep 3;40(17):3194-3198. doi: 10.1002/1521-3773(20010903)40:17<3194::AID-ANIE3194>3.0.CO;2-5.
2
Supramolecular Aggregates of Dendritic Cyclophanes (Dendrophanes) Threaded on Molecular Rods with Steroid Termini.带有甾体末端的分子棒上穿绕的树枝状环番（树状环）超分子聚集体。
Angew Chem Int Ed Engl. 1998 Dec 4;37(22):3154-3158. doi: 10.1002/(SICI)1521-3773(19981204)37:22<3154::AID-ANIE3154>3.0.CO;2-W.
3
Electrostatic Assembly of Dendrimer Electrolytes: Negatively and Positively Charged Dendrimer Porphyrins.树枝状聚合物电解质的静电组装：带负电荷和正电荷的树枝状卟啉
Angew Chem Int Ed Engl. 1998 Jun 19;37(11):1531-1534. doi: 10.1002/(SICI)1521-3773(19980619)37:11<1531::AID-ANIE1531>3.0.CO;2-T.
4
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5
Dendrimers in Supramolecular Chemistry: From Molecular Recognition to Self-Assembly.超分子化学中的树枝状大分子：从分子识别到自组装
Chem Rev. 1997 Aug 5;97(5):1681-1712. doi: 10.1021/cr9603892.
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