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月桂酸钾、1-癸醇和重水溶致液晶中接近双临界点的预转变标度。

Pretransitional scaling close to a double critical point in a potassium laurate, 1-decanol, and heavy water lyotropic liquid crystal.

作者信息

Licinio P, Santos M B L

机构信息

Departamento de Física, ICEx, UFMG, Caixa Postal 702, Belo Horizonte, Minas Gerais, Brazil.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2002 Mar;65(3 Pt 1):031714. doi: 10.1103/PhysRevE.65.031714. Epub 2002 Mar 1.

Abstract

Light scattering measurements were done close to the double critical point of the isotropic boundary of the lyotropic liquid crystal potassium laurate, 1-decanol, and heavy water. From scaling analysis we find susceptibility and correlation length exponents that are clearly higher than the mean-field values usually found in other studies on this and similar systems. In order to recover mean-field analysis, we use a parabolic version of the Landau-de Gennes free energy in account of the convex nature of the phase diagram. We also observe pretransitional characteristic domain sizes greater than the correlation length. Furthermore, we show that the transition goes into a new two-phase coexistence region, between the convex tips of pure isotropic and discotic nematic boundaries.

摘要

在溶致液晶月桂酸钾、1-癸醇和重水的各向同性边界的双临界点附近进行了光散射测量。通过标度分析,我们发现磁化率和关联长度指数明显高于在此系统及类似系统的其他研究中通常发现的平均场值。为了恢复平均场分析,考虑到相图的凸性,我们使用了朗道-德热纳自由能的抛物线形式。我们还观察到预转变特征畴尺寸大于关联长度。此外,我们表明,转变进入了一个新的两相共存区域,该区域位于纯各向同性和盘状向列相边界的凸端之间。

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