Slezak A, Wasik J, Jasik-Slezak J, Twardokes W
Wydział Zarzadzania, Politechnika Czestochowska w Czestochowie.
Polim Med. 2001;31(3-4):33-41.
In this paper the results of study flux gravidiffusive effect for a double-membrane osmotic-diffusive cell, in which series of two (Ml and M(r)), microporous and symmetrical flat polymeric membranes (Nephrophane and Cellulose IMP-1). These membranes separate three compartments (l, m, r) containing the heterogeneous and binary (aqueous glucose or ethanol solutions) or ternary (glucose solutions in 0.75 mole.l-1 aqueous ethanol solution or ethanol solutions in 0.1 mole.l-1 aqueous glucose solution) non-ionic solutions. The solution concentrations fulfil the condition Ckl > Ckm > Ckr. The inter-membrane compartment (m) consists of the infinitesimal layer of solution. The volume of compartment m and external compartment (l and r) fulfill the conditions Vm-->0 and Vl = Vr-->infinity respectively. The study of flux gravidiffusive effect for configurations A and B of the double-membrane osmotic-diffusive cell were elaborated. In configuration A solution was placed in compartment below membrane M(r) and water above membrane Ml. In configuration B solution was placed in compartment above membrane Ml and water below membrane Ml. These results are interpreted in terms of the convective instability that increases the diffusive permeability coefficients of complexes: concentration boundary layers/membrane Ml or M(r)/concentration boundary layer.
本文研究了双膜渗透扩散池的通量重力扩散效应,该池由两个(Ml和M(r))微孔对称平板聚合物膜(肾膜和纤维素IMP - 1)串联组成。这些膜分隔三个隔室(l、m、r),隔室内含有非均相二元(葡萄糖或乙醇水溶液)或三元(0.75摩尔·升⁻¹乙醇水溶液中的葡萄糖溶液或0.1摩尔·升⁻¹葡萄糖水溶液中的乙醇溶液)非离子溶液。溶液浓度满足条件Ckl > Ckm > Ckr。膜间隔室(m)由无限薄的溶液层组成。隔室m和外部隔室(l和r)的体积分别满足条件Vm→0和Vl = Vr→∞。阐述了对双膜渗透扩散池构型A和B的通量重力扩散效应的研究。在构型A中,溶液置于膜M(r)下方的隔室中,水置于膜Ml上方。在构型B中,溶液置于膜Ml上方的隔室中,水置于膜Ml下方。这些结果根据对流不稳定性进行解释,对流不稳定性增加了复合物的扩散渗透系数:浓度边界层/膜Ml或M(r)/浓度边界层。