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[一系列两个水平放置的扁平聚合物膜与三元非离子溶液的流动重力渗透效应]

[Streaming gravity-osmotic effect for a series of two flat polymeric membranes oriented horizontally and ternary non-ionic solutions].

作者信息

Slezak A, Wasik J, Jasik-Slezak J, Skrzekowska-Baran I

机构信息

Wydział Zarzadzania, Politechnika Czestochowska w Czestochowie.

出版信息

Polim Med. 2001;31(3-4):42-51.

Abstract

In this paper the results of study flux graviosmotic effect for a double-membrane system, in which two (Ml and M(r)), microporous and symmetrical flat polymeric membranes (Nephrophane and Cellulose IMP-1) separate three compartments (l, m, r) containing the heterogeneous and binary (aqueous glucose or ethanol solutions) or ternary (glucose solutions in 0.75 mole.l-1 aqueous ethanol solution or ethanol solutions in 0.1 mol.l-1 aqueous glucose solution) non-ionic solutions. In this system the solution concentrations fulfill the condition Ckl > Ckm > Ckr. The inter-membrane compartment (m) consists of the infinitesimal layer of solution. The volume of compartment m and external compartment (l and r) fulfill the conditions Vm-->0 and Vl = Vr-->infinity respectively. The calculations of flux graviosmotic effect for configurations A and B of the double-membrane osmotic-diffusive cell were elaborated. In configuration A solution was placed in compartment below membrane M(r) and water above membrane Ml. In configuration B solution was placed in compartment above membrane Ml and water below membrane Ml. These calculated results are interpreted in terms of the convective instability that increases the diffusive permeability coefficients of complexes: concentration boundary layers/membrane Ml or M(r)/concentration boundary layer.

摘要

本文研究了双膜系统的通量重力渗透效应,其中两片微孔对称平板聚合物膜(M1和M(r),分别为Nephrophane膜和纤维素IMP-1膜)分隔了三个隔室(l、m、r),隔室内含有非均相二元(葡萄糖或乙醇水溶液)或三元(0.75 mol·l⁻¹乙醇水溶液中的葡萄糖溶液或0.1 mol·l⁻¹葡萄糖水溶液中的乙醇溶液)非离子溶液。在该系统中,溶液浓度满足Ckl > Ckm > Ckr的条件。膜间隔室(m)由无限薄的溶液层组成。隔室m和外部隔室(l和r)的体积分别满足Vm→0和Vl = Vr→∞的条件。阐述了双膜渗透扩散池构型A和B的通量重力渗透效应的计算。在构型A中,溶液置于膜M(r)下方的隔室中,水置于膜M1上方。在构型B中,溶液置于膜M1上方的隔室中,水置于膜M1下方。这些计算结果根据对流不稳定性进行解释,对流不稳定性增加了复合物的扩散渗透系数:浓度边界层/膜M1或M(r)/浓度边界层。

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